105996-56-3

Basic information

• Product Name: Silane, [(3-ethoxy-3-methyl-1-cyclohexen-1-yl)oxy]trimethyl-
• CAS NO: 105996-56-3
• Molecular Formula: C12H24O2Si
• Molecular Weight: 228.407
• Mol File: 105996-56-3.mol

Chemical Properties

• CAS DataBase Reference: Silane, [(3-ethoxy-3-methyl-1-cyclohexen-1-yl)oxy]trimethyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, [(3-ethoxy-3-methyl-1-cyclohexen-1-yl)oxy]trimethyl-(105996-56-3)
• EPA Substance Registry System: Silane, [(3-ethoxy-3-methyl-1-cyclohexen-1-yl)oxy]trimethyl-(105996-56-3)

Safety Data

• Hazardous Substances Data: 105996-56-3(Hazardous Substances Data)

Upstream product

• 75-77-4 chloro-trimethyl-silane 
• 5323-87-5 3-Ethoxycyclohex-2-en-1-one 
• 15681-48-8 lithium dimethylcuprate 
• 89984-56-5 methyl manganese chloride 

Downstream Products

• 1193-18-6 3-methylcyclohexen-2-one 

Relevant articles and documents

ORGANOMANGANESE (II) REAGENTS XVI: COPPER-CATALYZED 1,4-ADDITION OF ORGANOMANGANESE CHLORIDES TO CONJUGATED ENONES

Copper-catalyzed conjugate addition of organomanganese chlorides to conjugated enones in THF, at 0 deg C, leads to the 1,4-addition products in high yields.The scope of the reaction is very large and the results are generally better than those obtained from organomagnesium compounds in the presence of a copper salts as well as from organocopper or cuprate reagents.Furthermore organomanganese chlorides are indisputably cheaper and more stable than the latter.

Organocopper conjugate addition reaction in the presence of trimethylchlorosilane

In the presence of TMSCl, the conjugate addition of organocuprates to various α, β-unsaturated esters, amides, ketones and nitriles is greatly improved. The reaction is faster, the yields are very high and the reaction is very clean.