1061180-99-1

Basic information

• Product Name: (4R,5R)-diisopropyl-2-phenyl-1,3,2-dioxaborolane-4,5-dicarboxylate
• Synonyms: (4R,5R)-diisopropyl-2-phenyl-1,3,2-dioxaborolane-4,5-dicarboxylate
• CAS NO: 1061180-99-1
• Molecular Weight: 320.15
• Mol File: 1061180-99-1.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (4R,5R)-diisopropyl-2-phenyl-1,3,2-dioxaborolane-4,5-dicarboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: (4R,5R)-diisopropyl-2-phenyl-1,3,2-dioxaborolane-4,5-dicarboxylate(1061180-99-1)
• EPA Substance Registry System: (4R,5R)-diisopropyl-2-phenyl-1,3,2-dioxaborolane-4,5-dicarboxylate(1061180-99-1)

Safety Data

• Hazardous Substances Data: 1061180-99-1(Hazardous Substances Data)

Upstream product

• 98-80-6 phenylboronic acid 
• 1061181-00-7 (-)-4,5-dimethyl-2-phenyl[1.3.2]dioxaborolane 
• 2217-15-4 L-(+)-diisopropyl tartrate 

Downstream Products

• 2217-15-4 L-(+)-diisopropyl tartrate 
• 76110-78-6 (3aS,4S,6S,7aR)-3a,5,5-trimethyl-2-phenylhexahydro-4,6-methanobenzo[d][1,3,2]dioxaborole 
• 4406-77-3 2-Phenyl-1,3,2-dioxaborinane 
• 5123-13-7 5,5-dimethyl-2-phenyl-1,3,2-dioxaborinane 
• 95843-97-3 2,4-dimethyl-2,4-pentanediol phenylboronic ester 
• 4406-73-9 diethanolamine phenylboronic ester 
• 73029-08-0 N-tert-butyldiethanolamine phenylboronic ester 
• 24388-23-6 2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole 
• 6638-70-6 (3aR,7aS)-2-phenyl-hexahydro-2H-1,3,2-benzodioxaborole 
• 7462-37-5 (3aR,6aS)-2-phenyl-hexahydrocyclopenta[d][1,3,2]dioxaborole 
• 4406-72-8 2-phenyl[1,3,2]dioxaborolane 

Relevant articles and documents

Mechanism and optimisation of the homoboroproline bifunctional catalytic asymmetric aldol reaction: Lewis acid tuning through in situ esterification

The use of homoboroproline as a bifunctional catalyst in the asymmetric aldol reaction has been investigated mechanistically, particularly with respect to tuning the Lewis acidity of boron by in situ esterification with mildly sigma-electron withdrawing diols such as hydrobenzoin and tartrate esters. The stability of simple cyclohexyl and cyclopentyl boronate diol esters shows that the 5-ring boronate esters are more stable, which sheds light on the mode of action of esterified homoboroproline catalyst in the enamine-mediated aldol reaction, which is also studied by NMR. The result is reaction optimisation to provide an efficient aldol reaction and a proposed mechanistic proposal. The Royal Society of Chemistry 2012.