106130-32-9Relevant academic research and scientific papers
ON THE MECHANISM OF THE DECARBOXYLATIVE REARRANGEMENT OF THIOHYDROXAMIC ESTERS
Barton, Derek H.R.,Crich, David,Potier, Pierre
, p. 5943 - 5946 (2007/10/02)
The thermal and photochemical decomposition of a typical thiohydroxamic ester (mixed anhydride) doubly labelled with deuterium has shown the photochemical reaction to be a radical chain process, whereas about 20percent of the thermal reaction involves a cage mechanism.An improved route to 1-hydroxy-5-phenylthiazolin-2-thione is reported.
