14181-82-9Relevant academic research and scientific papers
Synthesis, Isomerism, and Chemical Transformations of N-(2-Aryl-2-hydroxyiminoethyl) Azinium Salts
Artemov, V. A.,Shestopalov, A. M.,Litvinov, V. P.
, p. 548 - 553 (2007/10/03)
Quaternization of azines with ω-bromoacetophenone oximes yields N-(2-aryl-2-hydroxyiminoethyl)azinium salts, which exist as a mixtures of syn and anti isomers fixed due to interaction with the heteroring.The isomer ratio depends on the quaternization conditions and the substituent in the azine.N-(2-Aryl-2-hydroxyiminoethyl)azinium salts are deprotonated by bases, resulting in 1,4-elimination of the azine or ring closure into imidazoazines.
ON THE MECHANISM OF THE DECARBOXYLATIVE REARRANGEMENT OF THIOHYDROXAMIC ESTERS
Barton, Derek H.R.,Crich, David,Potier, Pierre
, p. 5943 - 5946 (2007/10/02)
The thermal and photochemical decomposition of a typical thiohydroxamic ester (mixed anhydride) doubly labelled with deuterium has shown the photochemical reaction to be a radical chain process, whereas about 20percent of the thermal reaction involves a cage mechanism.An improved route to 1-hydroxy-5-phenylthiazolin-2-thione is reported.
