106175-65-9Relevant academic research and scientific papers
98. A Regioselective Cyclohexannulation Procedure via Dienamine Cycloaddition. Synthesis of Functionalised Decalins
Snowden, Roger L.,Linder, Simon M.,Wuest, Manfred
, p. 892 - 905 (2007/10/02)
A regioselective cyclohexannulation procedure, whose key step involves the cycloaddition of dienamines 12-24 with methyl acrylate, allows the conversion of cycloalkanones 1-11 to bicyclic dienoates 25-37.The chemistry of 26 is briefly examined and, in the context of organoleptic studies concerning functionalised 5,5,9-trimethyldecalins, the transformation of 37 to ketones 44 and 46 as well as to acetates 53-56 is described.
DIENAMINES AS DIELS-ALDER DIENES. AN EFFICIENT CYCLOHEXANNULATION SEQUENCE.
Snowden, Roger L.,Wuest, Manfred
, p. 699 - 702 (2007/10/02)
An efficient cyclohexannulation sequence is described whose key step involves a Diels-Alder reaction between an (E)-dienamine and methyl acrylate.
