106184-25-2

Basic information

• Product Name: Benzene, 1-bromo-2-[2-(methylthio)ethenyl]-, (E)-
• CAS NO: 106184-25-2
• Molecular Formula: C9H9BrS
• Molecular Weight: 229.14
• Mol File: 106184-25-2.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Benzene, 1-bromo-2-[2-(methylthio)ethenyl]-, (E)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-bromo-2-[2-(methylthio)ethenyl]-, (E)-(106184-25-2)
• EPA Substance Registry System: Benzene, 1-bromo-2-[2-(methylthio)ethenyl]-, (E)-(106184-25-2)

Safety Data

• Hazardous Substances Data: 106184-25-2(Hazardous Substances Data)

Upstream product

• 766-46-1 2-bromo-1-ethynylbenzene 
• 1779-54-0 methylthiomethyl(triphenyl)phosphonium chloride 
• 6630-33-7 ortho-bromobenzaldehyde 

Relevant articles and documents

Studies of triphenylsilanethiol addition to alkynes: Preparation of vinyl sulfides

The scope and limitations of triphenylsilanethiol (1) a solid hydrogen sulfide equivalent, were investigated in free radical reactions to terminal alkynes. The triphenylsilylthioenol ether intermediate thus obtained was deprotected with Cs2CO3 in the presence of various electrophiles to yield mixtures of E and Z vinyl sulfides. The ratio of E and Z isomers could be controlled by varying the concentration of the starting alkynes.