106271-25-4

Basic information

• Product Name: N-(4-nitrophenyl)-2-(phenylmethylene)hydrazinecarbothioamide
• Synonyms: N-(4-nitrophenyl)-2-(phenylmethylene)hydrazinecarbothioamide
• CAS NO: 106271-25-4
• Molecular Weight: 300.341
• Mol File: 106271-25-4.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: N-(4-nitrophenyl)-2-(phenylmethylene)hydrazinecarbothioamide(CAS DataBase Reference)
• NIST Chemistry Reference: N-(4-nitrophenyl)-2-(phenylmethylene)hydrazinecarbothioamide(106271-25-4)
• EPA Substance Registry System: N-(4-nitrophenyl)-2-(phenylmethylene)hydrazinecarbothioamide(106271-25-4)

Safety Data

• Hazardous Substances Data: 106271-25-4(Hazardous Substances Data)

Upstream product

• 38985-70-5 4-(4-nitrophenyl)-3-thiosemicarbazide 
• 100-52-7 benzaldehyde 
• 2131-61-5 p-nitrophenyl isothiocyanate 
• 555-16-8 4-nitrobenzaldehdye 
• 5351-69-9 4-Phenyl-3-thiosemicarbazide 

Relevant articles and documents

Synthesis of Cyclic Azomethine Imines by Cycloaddition Reactions of N-Isocyanates and N-Isothiocyanates

Various nitrogen-substituted iso(thio)cyanates engage in [3 + 2]-cycloaddition reactions to form azomethine imines containing triazolone, triazole-thione, and pyrazole-thione cores. First, iminoisothiocyanates are shown to undergo aminothiocarbonylation reactions with strained alkenes, and a comparison with recently reported reactions of iminoisocyanates highlights their reduced reactivity. In contrast, amino(thio)carbonylation reactions of imines with iminoisocyanates and iminoisothiocyanates proved more efficient, providing access to triazolone and triazole-thione cores. The dipole products can be converted to valuable heterocyclic cores through simple derivatization reactions.