106357-37-3

Upstream product

• 106357-35-1 {Pt₂(CCHC₆H₅)(CCC₆H₅)(P(C₂H₅)3)4}⁽¹⁺⁾*BF₄^(1-)={Pt₂(CCHC₆H₅)(CCC₆H₅)(P(C₂H₅)3)4}BF₄ 

Downstream Products

• 122236-16-2 {Pt₂(CCHC₆H₅)(CCC₆H₅)(P(C₂H₅)3)3(NCS)} 
• 122236-15-1 {Pt₂(CCHC₆H₅)(CCC₆H₅)(P(C₂H₅)3)3(NCS)} 
• 122236-07-1 {Pt₂(CCHC₆H₅)(CCC₆H₅)(P(C₂H₅)3)3I} 
• 122236-08-2 {Pt₂(CCHC₆H₅)(CCC₆H₅)(P(C₂H₅)3)3(SC₆H₅)} 
• 122236-10-6 {Pt₂(CCHC₆H₅)(CCC₆H₅)(P(C₂H₅)3)3(SC₆Cl₅)} 
• 122236-13-9 {Pt₂(CCHC₆H₅)(P(C₂H₅)3)3I₂} 
• 122236-12-8 {Pt₂(CCHC₆H₅)(P(C₂H₅)3)3Br₂} 
• 122236-11-7 {Pt₂(CCHC₆H₅)(P(C₂H₅)3)3Cl₂} 
• 122236-14-0 {Pt₂(CCHC₆H₅)(P(C₂H₅)3)3(NCS)2} 
• 122236-06-0 {Pt₂(CCHC₆H₅)(CCC₆H₅)(P(C₂H₅)3)3Br} 

Relevant academic research and scientific papers

Reactions of coordinated molecules. 50. The preparation of homo- and heterodinuclear complexes containing μ-alkenylidene ligands

The formal addition of the Pt-H bond of the cationic complex [trans-Pt(H)(PEt3)2(acetone)]+ across the C-C triple bonds of alkynyl ligands affords cationic dinuclear complexes containing bridging alkenylidene ligands. The synthesis and characterization of eight such complexes are reported. On the basis of structural data for a member complex, these molecules are believed to possess Pt-Pt, Pt-Fe, Pt-Au, Pt-W, Pt-Ni, or Pt-Pd bonds. Diagnostic spectroscopic characterization data are provided. Furthermore, a similar addition of a Pt-Me bond across an acetylide ligand also affords a dinuclear μ-alkenylidene complex.