106417-87-2Relevant academic research and scientific papers
The Synthesis of Thionitrosodimethylamine (Me2NN=S) Complexes of Ruthenium, Osmium, and Iridium
Herberhold, Max,Hill, Anthony F.
, p. 105 - 112 (1986)
Neutral hydrido complexes ClH(PPh3)3 (= Ru(CO), Os(CO) and Ir(Cl) react with thionitrosodimethylamine, Me2NN=S, to give, ClH(SNNMe2)(PPh3)2 with H trans to Me2NN=S, while the hydrido cations cis,trans-H(SNNMe2)2(PPh3)2>+ are obtained from Me2NN=S and +, + and +, respectively.The coordinatively unsaturated aryl complexes Cl(p-tolyl)(PPh3)2 (= Ru(CO), Os(CO) and Os(CS) coordinate one molecule of Me2NN=S to give Cl(p-tolyl)(SNNMe2)(PPh3)2, the chloride ligands of which are labile.Spectroscopic data suggest that in all these complexes the Me2NN=S ligand adopts a η1(S) coordination mode.
