1064202-29-4Relevant academic research and scientific papers
INTRAMOLECULAR NITRILE OXIDE CYCLOADDITION ON CHIRAL OLEFINS : A STEREOCONTROLLED APPROACH TO β-KETOL PRECURSORS.
Annunziata, Rita,Cinquini, Mauro,Cozzi, Franco,Dondio, Gulio,Raimondi, Laura
, p. 2369 - 2380 (1987)
The intramolecular nitrile oxide cycloaddition reaction on (E) or (Z) olefins featuring a sulphur atom along the carbon chain connecting dipole and dipolarophile occurs with a poor to excellent anti stereoselectivity, which is mainly affected by the subst
ON STEREOCHEMISTRY OF OSMIUM TETRAOXIDE OXIDATION OF ALLYLIC ALCOHOL SYSTEMS. EMPIRICAL RULE
Cha, J. K.,Christ, W. J.,Kishi, Y.
, p. 2247 - 2256 (2007/10/02)
An empirical formulation is presented to predict the stereochemistry of major osmylation products of allylic alcohols and their derivatives.
