106449-99-4Relevant academic research and scientific papers
REACTIONS OF CIS-SILYL TIN OLEFINS: (ANTI-DENMARK) NAZAROV CYCLIZATION OF β-SILYL DIVINYL KETONES
Chenard, B. L.,Zyl, C. M. Van,Sanderson, D. R.
, p. 2801 - 2804 (1986)
Readily available silyl tin olefins efficiently couple with acid chlorides (Stille Reaction) to give β-silyl divinyl ketones.These ketones with large silyl groups (Et3Si, t-BuMe2Si) undergo Nazarov cyclizations wherein the silicon group is retained in the
