
Tetrahedron Letters p. 2801 - 2804 (1986)
Update date:2022-08-05
Topics:
Chenard, B. L.
Zyl, C. M. Van
Sanderson, D. R.
Readily available silyl tin olefins efficiently couple with acid chlorides (Stille Reaction) to give β-silyl divinyl ketones.These ketones with large silyl groups (Et3Si, t-BuMe2Si) undergo Nazarov cyclizations wherein the silicon group is retained in the
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(1986)