1064686-35-6Relevant academic research and scientific papers
Synthesis and characterization of new complexes formed by insertion of carbon disulphide in RuL3Cl3 (L=PPh3 and AsPh3)
Gogoi, Pradip K.,Borah, Geetika,Bharali, Nayanmoni,Saikia, Diganta
, p. 1113 - 1115 (2008/02/09)
Reaction of RuL3Cl3 (L=PPh3 and AsPh 3) with stoichiometric amount of CS2 in ethanol-dichloromethane mixed solvent systems at room temperature yields paramagnetic complexes of the type [RuL2Cl2(S 2COEt)]-The complexes have been characterized by conductance, IR, electronic, ESR spectral, magnetic moment measurement and thermal data as well as by elemental analysis. The appearance of three g-values in the ESR spectra reveal a highly distorted octahedral environment around ruthenium(III) ion with one bidented EtOCS2 ligand.
