106484-81-5Relevant academic research and scientific papers
Selective oxidation of alcohols at the benzylic position by benzeneseleninic anhydride
Toki, Naotoshi,Satoh, Tsuyoshi
, p. 1009 - 1012 (2007/10/03)
Benzeneseleninic anhydride in the presence of tert-butyl hydroperoxide in chlorobenzene at about 70°C is an effective oxidizing agent for the selective oxidation of alcohols at the benzylic position.
A catalytic amount of nickel(II) chloride hexahydrate and 1,2-ethanedithiol is a good combination for the cleavage of tetrahydropyranyl (THP) and tert-butyldimethylsilyl (TBS) ethers
Khan, Abu T.,Islam, Samimul,Choudhury, Lokman H.,Ghosh, Subrata
, p. 9617 - 9621 (2007/10/03)
Various THP and TBS ethers can be unmasked easily to the corresponding hydroxyl compounds in good yields by using a combination of a catalytic amount of nickel(II) chloride hexahydrate and 1,2-ethanedithiol at room temperature. In addition, alkyl TBS ethers can be hydrolyzed chemoselectively in the presence of aryl TBS ethers. Moreover, alkyl TBS ethers can be cleaved easily in the presence of alkyl or aryl THP ethers using the same conditions.
Synthesis of 3-(ω-Phenylalkyl)catechols, Phenolic Lipids found in Sap of the Burmese Lac Tree, via Directed Metallation
Furukawa, Yoshiaki,Yamagiwa, Yoshiro,Kamikawa, Tadao
, p. 1234 - 1235 (2007/10/02)
3-(ω-Phenylalkyl)catechols were synthesized via directed metallation.
