1065502-39-7

Basic information

• Product Name: C₁₄H₁₆N₂O₂S
• CAS NO: 1065502-39-7
• Molecular Weight: 276.359
• Mol File: 1065502-39-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₁₄H₁₆N₂O₂S(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₄H₁₆N₂O₂S(1065502-39-7)
• EPA Substance Registry System: C₁₄H₁₆N₂O₂S(1065502-39-7)

Safety Data

• Hazardous Substances Data: 1065502-39-7(Hazardous Substances Data)

Upstream product

• 6330-09-2 5-benzyl-2-thiohydantoin 
• 108-24-7 acetic anhydride 
• 122-51-0 orthoformic acid triethyl ester 

Relevant articles and documents

A one-pot chemoselective S-alkylation and acetylation of thiohydantoins using the alkyl orthoformate-ZnCl2-Ac2O reagent system

The chemoselective S-alkylation of 2-thiohydantoins is reported. The methodology involves the use of alkyl orthoformates (trimethyl and triethyl) as alkylating agents, which in the presence of Ac2O and ZnCl2 chemoselectively alkylate the thio group whilst other nucleophilic groups present in the thiohydantoins are acetylated simultaneously in moderate to high yields. A plausible mechanism for this reaction is delineated.