106552-38-9

Upstream product

• 116245-97-7 3,7-Bis-(4-chloro-phenyl)-5,5-diphenyl-5,6-dihydro-4H-[1,2]diazepine 
• 530-48-3 1,1-Diphenylethylene 
• 122-01-0 4-chloro-benzoyl chloride 
• 35556-63-9 1,1-diphenyl-3-p-chlorophenylpropargyl alcohol 
• 909120-14-5 N,N'-Bis-[1-(4-chloro-phenyl)-eth-(Z)-ylidene]-hydrazine 

Downstream Products

• 1251472-03-3 C₂₁H₁₇ClO 

Relevant academic research and scientific papers

β-Selective Aroylation of Activated Alkenes by Photoredox Catalysis

Late-stage synthesis of α,β-unsaturated aryl ketones remains an unmet challenge in organic synthesis. Reported herein is a photocatalytic non-chain-radical aroyl chlorination of alkenes by a 1,3-chlorine atom shift to form β-chloroketones as masked enones

Enantioselective reduction of ketones and imines catalyzed by (CN-Box)ReV-oxo complexes

The development and application of chiral, non-racemic ReV-oxo complexes to the enantioselective reduction of prochiral ketones is described. In addition to the enantioselective reduction of prochiral ketones, we report the application of these complexes to 1) a tandem Meyer-Schuster rearrangement/reduction to access enantioenriched allylic alcohols and 2) the enantioselective reduction of imines.