1065653-61-3Relevant academic research and scientific papers
Catalytic asymmetric deprotonation of a phosphine borane: comparison of two-ligand and one-ligand catalysis
Canipa, Steven J.,O'Brien, Peter,Taylor, Sven
, p. 2407 - 2412 (2009)
The catalytic asymmetric deprotonation of tert-butyldimethylphosphine borane using s-BuLi or n-BuLi and sub-stoichiometric amounts of (-)-sparteine under one-ligand and two-ligand manifolds has been investigated. Using s-BuLi, slightly higher enantioselec
Catalytic asymmetric deprotonation of phosphine boranes and sulfides as a route to P-stereogenic compounds
Gammon, Jonathan J.,Canipa, Steven J.,O'Brien, Peter,Kelly, Brian,Taylor, Sven
, p. 3750 - 3752 (2009/02/07)
A comparison between phosphine boranes and sulfides in their catalytic asymmetric deprotonation using organolithiums and sub-stoichiometric amounts of (-)-sparteine has revealed superior catalytic efficiency in the phosphine sulfide deprotonation. The Royal Society of Chemistry.
