106576-42-5Relevant academic research and scientific papers
Amino acid and water-driven tunable green protocol to access S-S/C-S bonds via aerobic oxidative coupling and hydrothiolation
Shard, Amit,Kumar, Rajesh,Saima,Sharma, Nidhi,Sinha, Arun K.
, p. 33399 - 33407 (2014)
A green methodology utilizing a natural supplement such as l-arginine in conjunction with water and oxygen led to oxidative coupling of thiols into disulfides (S-S bond) whereas thiol-yne coupling to access vinyl sulfides (C-S bond) was facilitated in a nitrogen atmosphere. The tunable protocol offers several advantages such as low catalyst loading, high yields, clean reaction, no over-oxidation of the S-S bond besides being metal/base/waste-free. The synthesis of ubiquitous cystine and glutathione disulfide in the same catalytic system is an added advantage and the catalytic system has been recycled up to seven times. the Partner Organisations 2014.
Synthesis and Structure of Aromatic and Heterocyclic Tellurium Compounds. XXXIII. Synthesis of 2-Aryltellurovinyl Aldehydes and Ketones and Stereochemistry of Nucleophilic Substitution at the Vinyl Carbon Atom
Sadekov,Rivkin,Zakharov,Minkin
, p. 1022 - 1030 (2007/10/03)
2-Aryltellurovinyl aldehydes and ketones were synthesized by reaction of 2-chlorovinyl carbonyl compounds and (2-acylvinyl)triethylammonium chlorides with arenetellurolate ions. Bis(aroylvinyl) tellurides were obtained by reaction of 2-aroylvinyl chloride
