21860-49-1Relevant academic research and scientific papers
INDUCTION PAR LA LUMIERE DE L'OXYDATION DES COMPLEXES Η3-ALLYLPALLADIUM PAR L'OXYGENE MOLECULAIRE
Muzart, J.,Pale, P.,Pete, J.P.,Riahi, A.
, p. 731 - 739 (2007/10/02)
Irradiation at λ=366 nm of oxygenated solutions of η3-allylpalladium complexes leads to unsaturated carbonyl compounds.Substitution of the η3-allyl ligand by an electron withdrawing group could induce a regioselective oxidation of the allylic position farthest from this group.The efficiency of these reactions is sensible to the nature of the solvent.
PHOTOOXYDATION REGIOSELECTIVE DE COMPLEXES η3-ALLYLPALLADIUM: ACCES A DES COMPOSES CARBONYLES α,β-INSATURES FONCTIONNALISES EN γ
Muzart, J.,Pale, P.,Pete, J. P.
, p. 4567 - 4568 (2007/10/02)
Irradiation of oxygenated solutions of η3-allylpalladium complexes, formed from alkenes substituted in α or β-position by an electron-withdrawing group, leads to a regioselective oxidation of the allyl group.
