106584-12-7Relevant academic research and scientific papers
PdCl2(CH3CN)2-catalyzed regioselective C-H olefinations of 2-amino biaryls with vinylsilanes as unactivated alkenes
Sun, Qiao-Ying,Li, Zhao,Xu, Zheng,Zheng, Zhan-Jiang,Cao, Jian,Yang, Ke-Fang,Cui, Yu-Ming,Xu, Li-Wen
supporting information, p. 6229 - 6232 (2019/06/07)
The first example of palladium-catalyzed chelation-assisted C-H olefination of 2-amino biaryls using readily available vinylsilanes as unactivated olefinating reagents has been developed, affording valuable arylated vinylsilane compounds in moderate to excellent yields and with exclusive (E)-selectivities.
REARRANGEMENT OF 2-HETARYLALKYLPYRIDINIUM SALTS
Rumyantsev, A. N.,Terenin, V. I.,Yudin, L. G.
, p. 300 - 303 (2007/10/02)
The rearrangement of 2-thienyl- and 2-furylalkylpyridinium salts to the corresponding anilines by the action of methylammonium sulfites has been studied.It has been shown that the rearrangement of these salts is accompanied in many cases by the formation of phenols and dealkylation products.The influence of the length of the alkyl chain between the heterocyclic rings on the ratio of the rearrangement products has been investigated.
