106650-98-0

Upstream product

• 1122-91-4 4-bromo-benzaldehyde 
• 1730-25-2 allylmagnesium bromide 
• 106-95-6 allyl bromide 
• 24850-33-7 allyltributylstanane 
• 762-72-1 allyl-trimethyl-silane 
• 7393-43-3 tetraallyl tin 
• 55605-27-1 (4-bromophenyl)methylenediacetate 
• 383-67-5 allyl trifluoroacetate 
• 28115-12-0 (E)-1-(4-bromophenyl)-N-(4-methoxyphenyl)methanimine 
• 2622-05-1 allylmagnesium bromide 
• 591-87-7 Allyl acetate 
• 873-75-6 4-bromobenzenemethanol 
• 25062-46-8 4-bromobenzaldehyde oxime 
• 72824-04-5 2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 

Downstream Products

• 71787-53-6 1-(p-cyanophenyl)-3-buten-1-ol 
• 184165-64-8 1-(4-bromophenyl)-3-buten-1-one 
• 1033605-65-0 C₂₀H₂₀Br₂O 
• 114095-76-0 1-bromo-4-(1-methoxy-but-3-enyl)benzene 
• 1210066-93-5 (E)-4-(4-bromophenyl)-4-hydroxybut-2-enyl propionate 
• 1242076-94-3 (E)-1-(3-azidobut-1-enyl)-4-bromobenzene 
• 1242077-03-7 (E)-1-(4-(4-bromophenyl)but-3-en-2-yl)-4-phenyl-1H-1,2,3-triazole 
• 1251857-72-3 (E)-1-bromo-4-(3-tosylbut-1-enyl)benzene 
• 1280224-76-1 (E)-N-(4-(4-bromophenyl)but-3-en-2-yl)-4-methylbenzenesulfonamide 
• 1318230-50-0 2-(1-(4-bromophenyl)but-3-enyloxy)acetic acid 
• 1373441-38-3 (2R,4s,6S)-2,6-bis(4-bromophenyl)-4-tosyloxytetrahydropyran 
• 1416168-36-9 (E)-6-(4-(4-bromophenyl)-4-oxobut-1-enyl)-2,2-dimethyl-4H-1,3-dioxin-4-one 
• 1416168-46-1 (E)-6-(4-(4-bromophenyl)-4-hydroxybut-1-enyl)-2,2-dimethyl-4H-1,3-dioxin-4-one 

Relevant academic research and scientific papers

A joint experimental and theoretical study of the palladium-catalyzed electrophilic allylation of aldehydes

(Chemical Equation Presented) Palladium-catalyzed electrophilic allylation of aldehydes with allylstannanes has been proposed in the literature as a model reaction illustrating the potential of nucleophilic η1-allyl palladium pincer complexes t

Palladium- and Platinum-catalysed Addition of Aldehydes with Allylstannanes

The reaction of allylic stannanes 1 with aldehydes 2 (or a ketone) takes place in the presence of catalytic amounts of PdCl2(PPh3)2 or PtCl2(PPh3)2 to give the corresponding homoallyl alcohols 3 in good to high yields.

β-Cyclodextrin promoted allylation of aldehydes with allyltributyltin under supramolecular catalysis in water

A novel and highly efficient allylation of aldehydes using allyltributyltin has been developed in aqueous medium catalyzed by β-cyclodextrin in the presence of HCl without any metal catalysts to afford the corresponding homoallylic alcohols in good yields

An organoantimony complex with intramolecular N?→?Sb coordination as effective and recyclable catalyst for the allylation of aldehydes with tetraallyltin

An air-stable hypervalent organoantimony (III) triflate complex (PhN(CH2C6H4)2SbOSO2CF3) having intramolecular N?→?Sb coordination was synthesized and characterized by techniques such as s

A SeCSe-Pd(II) pincer complex as a highly efficient catalyst for allylation of aldehydes with allyltributyltin

An air- and moisture-stable SeCSe-Pd(II) pincer complex was synthesized and found to catalyze the nucleophilic allylation of aldehydes with allyltributyltin. The allylation of a variety of aromatic and aliphatic aldehydes to give the corresponding homoall

Rapid synthesis of homoallylic alcohol from aldehyde with allyltributylstannane under solvent-free conditions

A catalytic amount (2 mol %) of phosphotungstic acid (PTA) is sufficient to synthesize homoallylic alcohol in excellent yields from aldehyde with allyltributylstannane upon grinding under solvent-free reaction conditions. Easy handling, very short reactio

Diallylaluminium-N,N-dimethylaminoethanolate, the first stable allyl-alane suitable for additions to aldehydes, ketones and imines

The reaction of AlCl3 with lithium-N,N-dimethylaminoethanolate (3) in a 1:1 ratio yields the corresponding organo-aluminium chloride [Cl2Al(μ-OCH2CH2NMe2)] 2 (1) from which the diallyl derivative [(CH2=CHCH2)2Al(μ-OCH2CH 2NMe2)]2 (4) was synthesized by treatment with 2 equiv. of allyl magnesium bromide. The structures of 1 and 4 were deduced from the 1H, 13C, 27Al NMR spectra and confirmed by X-ray structural determination. The allyl aluminium complex 4 was found to be a useful reagent for the transfer of one allyl group to aldehydes, imines and enones. The 1,2-addition products are formed in high yields.

Bi-mediated allylation of aldehydes in [bmim][Br]: A mechanistic investigation

The inexpensive room temperature ionic liquid (RTIL), [bmim][Br] has been found to be a superior medium for the Bi-mediated Barbier-type allylation of aldehydes compared to other conventional solvents. It plays the dual role of a solvent and a metal activ

The fate of bis(η3-allyl)palladium complexes in the presence of aldehydes (or imines) and allylic chlorides: Stille coupling versus allylation of aldehydes (or imines)

The mere presence or absence of PPh3 suffices to control the reactivity of bis(η3-allyl)palladium complexes. In the absence of PPh3 they undergo chemoselective allylic addition to aldehydes or imines, even in the presence of allylic chlorides, whereas in the presence of PPh3 the Stille coupling reaction takes place chemoselectively, even when aldehydes or imines are also present (see scheme).

Preparation of allyltin reagents grafted on solid support: Clean and easily recyclable reagents for allylation of aldehydes

The preparation of polymer-supported allyltin reagents was shown to be possible for both unfunctionalized and functionalized allyl units. These reagents were treated with aldehydes in the presence of cerium(III) or indium(III) salts to afford high yields