1067-97-6

Basic information

• Product Name: tributylstannanylium hydroxide
• Synonyms: Stannane, (hydroxy)tributyl-; NSC 65224; Stannane, tributylhydroxy-; Tin, tributyl-, hydroxide; Tin, tributylhydroxy-; tributylstannanyl hydrate; tributylstannanol; stannanylium, tributyl-, hydroxide (1:1)
• CAS NO: 1067-97-6
• Molecular Formula: C₁₂H₂₈OSn
• Molecular Weight: 307.0601
• EINECS: 213-939-8
• Mol File: 1067-97-6.mol
• Article Data: 5

Chemical Properties

• Boiling Point: 304.947°C at 760 mmHg
• Flash Point: 138.227°C
• Vapor Pressure: 0mmHg at 25°C
• CAS DataBase Reference: tributylstannanylium hydroxide(CAS DataBase Reference)
• NIST Chemistry Reference: tributylstannanylium hydroxide(1067-97-6)
• EPA Substance Registry System: tributylstannanylium hydroxide(1067-97-6)

Safety Data

• Hazardous Substances Data: 1067-97-6(Hazardous Substances Data)

Usage

General Description

Tributylstannanylium hydroxide is a chemical compound that is used as a Lewis acid catalyst in various organic reactions. It is an organotin compound, composed of a tributylstannyl group attached to a hydroxide ion. tributylstannanylium hydroxide is commonly used in the synthesis of various organic compounds, including esters, ethers, and amino acids. It is known for its high reactivity and strong affinity for electron-rich compounds, making it an efficient catalyst for a wide range of chemical transformations. However, it is also important to handle tributylstannanylium hydroxide with caution, as organotin compounds are known to be toxic and can have harmful effects on the environment.

Upstream product

• 24850-33-7 allyltributylstanane 
• 109-63-7 trifluoroborane diethyl ether 
• 123-38-6 propionaldehyde 
• 1461-22-9 tributyltin chloride 
• 112520-99-7 tributyl(cyclohex-2-en-1-yl)stannane 
• 619-58-9 4-iodobenzoic acid 
• 17955-46-3 trimethylsilyltributyltin 
• 7342-47-4 tributyltin iodide 
• 7732-18-5 water 
• 56-35-9 bis(tri-n-butyltin)oxide 
• 103-82-2 phenylacetic acid 
• 100-51-6 benzyl alcohol 
• 813-19-4 bis(tri-n-butyltin) 
• 26138-28-3 phenylytterbium iodide 

Downstream Products

• 994-89-8 tributylethynyltin 
• 14275-61-7 1,2-bis(tributylstannyl)ethylene 
• 14275-60-6 Dibutyl-bis-(2-tributylstannyl-vinyl)-zinn 
• 1461-22-9 tributyltin chloride 
• 34833-34-6 C₂₀H₃₄N₄Sn 
• 139257-31-1 C₆H₄(CO)2NCHCH₂C₆H₄OHCOOSn(C₄H₉)3 
• 139257-39-9 C₆H₄(CO)2NCH₂CONHCHCH₂(C₆H₅)COOSn(C₄H₉)3 
• 139257-36-6 C₆H₄(CO)2NC₆H₃OHCOOSn(C₄H₉)3 
• 139257-46-8 CH₃(C₆H₄)SO₂NHCHCH₂CH(CH₃)2COOSn(C₄H₉)3 
• 139257-23-1 C₆H₄(CO)2NCHCH₂(C₆H₅)COOSn(C₄H₉)3 
• 139257-45-7 (C₆H₅)CONHCHCH(CH₃)2COOSn(C₄H₉)3 
• 135532-14-8 bis-tributyltin(tricyclohexylstannyloxysulphonyl)maleate 
• 994-71-8 bis(tributylstannyl)acetylene 
• 29140-32-7 Fumarsaeure-bis- 

Relevant articles and documents

Green synthetic approach to 5-substituted-1h-tetrazoles via recycle and reuse of tributyltin chloride

A simple, safe and efficient process for the recycle of tributyltin chloride from tributyltin hydroxide is developed and its reuse in the synthesis of 5-substituted-1H-tetrazoles is successfully demonstrated, which paved a way to reduce the toxic tin waste significantly. Recycling of tributyltin chloride is possible over six cycles without loss of its activity.

Cleavage of Sn-Sn Bonds in Hexaalkyl(aryl)stannanes under the Action of Yb(II) Derivatives

Ytterbium(II) derivatives MeYbI, PhYbI, and YbI2 cleave the Sn-Sn bond in distannanes R′3-SnR′3 (R′ = n-Bu, Ph) to give heterobimetallic derivatives R′3SnYbI, which were identified by products of their hydrolysis, exchange with R″3EHlg (R″ = Ph, Me; E = Ge, Si, Sn) and cross coupling with MeI in the presence of NiCl2(Ph3P)2.