106726-58-3Relevant academic research and scientific papers
Synthesis and Isolation of Aryl Thioaldehyde S-Oxides
Bonini, Bianca F.,Mazzanti, Germana,Zani, Paolo,Maccagnani, Gaetano,Barbaro, Gaetano,et al.
, p. 964 - 965 (1986)
(E)-Phenyl and (E)-(p-tolyl) trimethylsilyl thioketone S-oxides can be easily and stereospecifically protodesilylated into the corresponding (Z)-aryl thioaldehyde S-oxides; these stable liquid lachrimatory compounds show good reactivity as heterodienophil
Chemistry of Silylated Thioketones. Part 2. Cycloaddition Reactions with 1,3-Dienes
Bonini, Bianca F.,Lenzi, Alberto,Maccagnani, Gaetano,Barbaro, Gaetano,Giorgianni, Patrizia,Macciantelly, Dante
, p. 2643 - 2646 (2007/10/02)
Trimethylsilylphenyl- and triphenylsilylphenyl thioketones easily undergo -cycloadditions with cyclic and open chain 1,3-dienes at room temperature to give silylated thiabicycloheptenes and dihydrothiopyrans in very good yields.With cyclopentadiene the reaction produces exclusively the endo-silylated adducts.Sulphur oxidation and desilylation of the adducts were also investigated.
