106762-05-4Relevant articles and documents
A new approach for the transformation of alkenes to pyrrolines via aziridine intermediates
Ajay Kumar,Lokanatha Rai,Umesha
, p. 6993 - 6996 (2001)
Alkenes (1) reacts with chloramine-T in presence of the catalyst silver nitrate to afford aziridines (2). The aziridines underwent ring expansion with the acrylo nitrile or ethyl acrylate (3) in the presence of solid sodium hydroxide to form pyrrolines (4) in 40-58% yield.
Silyl-Substituted Thioimidates as Nitrile Ylide Equivalents
Padwa, Albert,Gasdaska, John R.,Haffmanns, Gunter,Rebello, Hector
, p. 1027 - 1035 (2007/10/02)
Treatment of silyl-substituted thioimidates with silver fluoride in the presence of a trapping agent produces dipolar cycloadducts formally derived from nitrile ylides.The ratio of cycloadducts obtained from the reaction of unsymmetrically substituted dip