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1-Mercapto-2-propanol is a chain transferring agent that is part of the hydrogen-bonded 1,2-propanols series. It is known for its ability to form polymeric chains with low molecular weight and short chain length. This unique property makes it a versatile compound in various applications.

1068-47-9

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1068-47-9 Usage

Uses

Used in Electrochemical Applications:
1-Mercapto-2-propanol is used as a self-assembled monolayer on gold surfaces, which has potential applications in electrochemistry. This allows for improved control and manipulation of electrochemical processes, making it a valuable component in the development of advanced electrochemical devices.
Used in Chemical Analysis:
1-Mercapto-2-propanol serves as a chiral agent, which is essential in the chemical analysis of enantiomers. Its ability to interact with chiral molecules enables more accurate and precise determination of enantiomeric compositions, contributing to the advancement of analytical chemistry and the development of enantioselective processes.

Check Digit Verification of cas no

The CAS Registry Mumber 1068-47-9 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 1,0,6 and 8 respectively; the second part has 2 digits, 4 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 1068-47:
(6*1)+(5*0)+(4*6)+(3*8)+(2*4)+(1*7)=69
69 % 10 = 9
So 1068-47-9 is a valid CAS Registry Number.
InChI:InChI=1/C3H8OS/c1-3(4)2-5/h3-5H,2H2,1H3

1068-47-9 Well-known Company Product Price

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  • Aldrich

  • (328375)  1-Mercapto-2-propanol  95%

  • 1068-47-9

  • 328375-5G

  • 3,683.16CNY

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1068-47-9SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 12, 2017

Revision Date: Aug 12, 2017

1.Identification

1.1 GHS Product identifier

Product name 1-sulfanylpropan-2-ol

1.2 Other means of identification

Product number -
Other names 2-hydroxypropyl mercaptane

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:1068-47-9 SDS

1068-47-9Related news

Structural evolution of self-assembled monolayer of 1-MERCAPTO-2-PROPANOL (cas 1068-47-9) on Au(1 1 1) in a N2 flow: an electrochemical and STM study07/24/2019

The structural evolution of 1-mercapto-2-propanol layer on Au(1 1 1) during a treatment in a N2 flow was investigated using STM and cyclic voltammetry. The pristine layer showed a striped structure of (2√3×√3) with coverage of 0.33. As the SAM was treated in the N2 flow, the superlattice evol...detailed

1068-47-9Relevant academic research and scientific papers

Kinetic peculiarities of the reaction of liquefied hydrogen sulfide with propylene oxide

Malievskii,Shokina

, p. 1072 - 1078 (1999)

The kinetics of the liquid-phase reaction of hydrogen sulfide with propylene oxide was studied. In the presence of excess epoxide, the reaction occurred in two successive macrostages: (1) formation of 2-hydroxypropane-1-thiol and (2) formation of 1,1′-di(2-hydroxypropyl) sulfide. Both of the stages are autocatalytic. 2-Hydroxypropane-1-thiol was mainly formed in the presence of excess H2S. The overall third order of the reaction (the first with respect to each reagent and to 2-hydroxypropane-1-thiol) was found. A kinetic scheme was proposed, and the rate constants of particular stages were calculated. The influence of various catalysts (active carbon, ion-exchange resins, metal oxides, and others) was studied, and the relative efficiency of some of them was determined.

The efficient conversion of H2S into mercaptan alcohols mediated in protic ionic liquids under mild conditions

Hu, Xingbang,Shi, Mingzhen,Tu, Zhuoheng,Wu, Youting,Xiong, Wenjie,Zhang, Xiaomin

supporting information, p. 7969 - 7975 (2021/11/01)

The resource utilization of hydrogen sulfide (H2S) is an important and promising topic in energy chemical engineering. Previous products developed in our group through H2S conversion are sulfur or mercaptan acids. An alternative way to convert H2S is still desirable. Herein, we have developed a green and mild method to convert H2S into mercaptan alcohols by the addition reaction with epoxide mediated in tertiary amine-functionalized protic ionic liquids (PILs). Reaction kinetics, substrate scope, and regeneration experiments have all been explored. Almost quantitative conversion of substrates was realized with a catalytic loading of PILs at 30 °C. Water extraction was used to recycle the catalysts from the reaction system. It is believed that the excellent results, together with its operational simplicity and the ability to successively reuse the catalyst, make this new methodology environmentally benign and cost-effective. The generality of the H2S resource methodology gives it potential for application on an industrial scale.

Novel triethylamine catalyzed S → O acetyl migration reaction to generate candidate thiols for construction of topological and functional sulfur-containing polymers

Wang, Gang,Peng, Li,Zheng, Yaochen,Gao, Yanqin,Wu, Xuedong,Ren, Tianhui,Gao, Chao,Han, Jin

, p. 5674 - 5679 (2015/02/05)

We describe a novel triethylamine catalyzed S → O acetyl migration reaction for yielding thiol compounds under mild conditions through the formation of a transitional 5-membered ring. A series of epoxy compounds have been transformed into their thiol counterparts which could be used for construction of topological and functional sulfur-containing polymers. The one-pot two-step processes including the S → O acetyl migration and the following thiol-click reactions avoided separation of thiol intermediates. Applying these processes on a new-type latent polythiols overcomes crosslinking problem usually met in preparation of multithiol compounds due to the formation of disulfide bonds. This journal is

Enzymatic kinetic resolution of organochalcogenides in supercritical CO2

Gariani, Rogério A.,Luengo, Fernando A.G.,Vale, Luiz A.S.,Bazito, Reinaldo C.,Comasseto, Jo?o V.

supporting information; experimental part, p. 3336 - 3338 (2011/06/28)

1-(Phenylthio)-, 1-(phenylseleno)- and 1-(phenyltelluro)-propan-2-ol were efficiently resolved by CAL-B in sc-CO2.

Regio- and enantioselective ring-opening of epoxides with HMDST: A straightforward access to 1,2-mercaptoalcohols

Degl'Innocenti, Alessandro,Capperucci, Antonella,Cerreti, Arianna,Pollicino, Salvatore,Scapecchi, Serena,Malesci, Irene,Castagnoli, Giulio

, p. 3063 - 3066 (2007/10/03)

TBAF-catalyzed reaction of a range of substituted epoxides with hexamethyldisilathiane smoothly affords a direct and simple access to β-mercaptoalcohols in a highly regio- and stereo-selective way. Georg Thieme Verlag Stuttgart.

Triphendioxazine dyestuffs

-

, (2008/06/13)

The novel triphendioxazine dyestuffs of the formula STR1 in which the substituents R, R', T1, T2, X, Y and n have the meanings given in the description are highly suitable for the dyeing and printing of cellulose-containing or amido-containing material.

Synthesis and Insecticidal Activity of Oxazaphospholidines, Oxathiaphospholanes, and Thiazaphospholidines

Wu, Shao-Yong,Hirashima, Akinori,Takeya, Ryuko,Eto, Morifusa

, p. 2911 - 2918 (2007/10/02)

Fifty-five new five-membered cyclic organophosphorus compounds including oazaphospholidines, thiazaphospholidines, and oxathiaphospholanes were synthesized, which have substituents at 4- or/and 5-positions besides at the 2-position.The thiazaphospholidines showed the highest insecticidal activity followed by oxathiaphospholanes and oxazaphospholidines.The position preference of substituents in insecticidal activity was most obvious in the oxazaphospholidines.It was preferable for insecticidal activity to have the substituent near the more basic atom: the 4-position for thiazaphospholidine and oxazaphospholidine, the 5-position for oxathiaphospholane, with the exception of 4- or 5-phenyl oxazaphospholidine.

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