106820-49-9

Upstream product

• 106820-48-8 (3aS,4S,6aR)-4-(tert-Butyl-diphenyl-silanyloxymethyl)-3,3a,4,6a-tetrahydro-furo[3,4-c]pyrazol-6-one 
• 193814-41-4 (3S,4R,5S)-5-(tert-Butyl-diphenyl-silanyloxymethyl)-4-methyl-3-phenylselanyl-dihydro-furan-2-one 
• 32780-06-6 (5S)-5-(hydroxymethyl)-2-oxo-tetrahydrofuran 
• 102717-29-3 (5S)-5-({[tert-butyl(diphenyl)silyl]oxy}methyl)dihydrofuran-2(3H)-one 
• 58479-61-1 tert-butylchlorodiphenylsilane 
• 5336-08-3 D-Ribono-1,4-lactone 
• 193814-38-9 3-((S)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-butyric acid ethyl ester 
• 193814-39-0 4RS,5S-5-Hydroxymethyl-4-methyl-4,5-dihydro-2(3H)-furanon 
• 103233-14-3 (4S,5S)-5-({[tert-butyl(diphenyl)silyl]oxy}methyl)-4-methyldihydrofuran-2(3H)-one 
• 99315-75-0 (-)-5-O-(diphenyl-t-butylsilyl)-2,3-O-(thiocarbonyl)-D-ribono-1,4-lactone 
• 92512-33-9 (3R,4S,5R)-5-((tert-butyldiphenylsilyloxy)methyl)-3,4-dihydroxydihydrofuran-2(3H)-one 
• 106731-86-6 (S)-5-(tert-Butyl-diphenyl-silanyloxymethyl)-3-phenylselanyl-dihydro-furan-2-one 
• 56-86-0 L-glutamic acid 
• 99315-76-1 (5S)-5-(tert-butyldiphenylsiloxymethyl)-2(5H)-furanone 

Downstream Products

• 106820-50-2 2,3-dideoxy-3-C-methyl-5-O-tert-butyldiphenylsilyl-D-threo-pentono-1,4-lactone 
• 106820-54-6 (3R,4S,5R)-5-(tert-Butyl-diphenyl-silanyloxymethyl)-3,4-dihydroxy-4-methyl-dihydro-furan-2-one 
• 106820-51-3 (3R,4R,5S)-5-(tert-Butyl-diphenyl-silanyloxymethyl)-3,4-dimethyl-dihydro-furan-2-one 
• 106820-53-5 (3R,4S,5S)-5-(tert-Butyl-diphenyl-silanyloxymethyl)-3-hydroxy-3,4-dimethyl-dihydro-furan-2-one 
• 106820-52-4 (2R,3R,4S)-5-[(tert-butyldiphenylsilyl)oxy]-2-hydroxy-3-methyl-4-pentanolide 

Relevant academic research and scientific papers

Synthesis of γ-lactone derivatives as a key intermediate for the spiroketal fragment in calyculin A

A simple and safe route to the D-xylone-l,4-lactone derivative 3, a key intermediate for the synthesis of the spiroketal fragment in calyculin A (I) has been explored without the use of hazardous diazomethane on a large scale.

STEREOCHEMICAL CONTROL OF NATURE'S BIOSYNTHETIC PATHWAYS: A GENERAL STRATEGY FOR THE SYNTHESIS OF POLYPROPIONATE-DERIVED STRUCTURAL UNITS FROM A SINGLE CHIRAL PROGENITOR

A general strategy that permits the stereocontrolled construction of acyclic chains containing vicinal and/or alternating alkyl and hydroxy substituents is presented.Structural subunits of ionomycin were synthesized from a common chiral intermediate.

A Versatile Protocol for the Stereocontrolled Elaboration of Vicinal Secondary and Tertiary Centers of Relevance to Natural Product Synthesis

Chiral butenolides derived from L-glutamic acid, D-ribonolactone, or D-mannitol are versatile templates from the stereocontrolled introduction of functional groups.Vicinal and/or alternating patterns of secondary and tertiary substitution can be attained