1068441-41-7

Basic information

• Product Name: 5-(2-bromobenzyloxy)-2,4-di-tert-butylphenol
• Synonyms: 5-(2-bromobenzyloxy)-2,4-di-tert-butylphenol
• CAS NO: 1068441-41-7
• Molecular Weight: 391.348
• Mol File: 1068441-41-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 5-(2-bromobenzyloxy)-2,4-di-tert-butylphenol(CAS DataBase Reference)
• NIST Chemistry Reference: 5-(2-bromobenzyloxy)-2,4-di-tert-butylphenol(1068441-41-7)
• EPA Substance Registry System: 5-(2-bromobenzyloxy)-2,4-di-tert-butylphenol(1068441-41-7)

Safety Data

• Hazardous Substances Data: 1068441-41-7(Hazardous Substances Data)

Upstream product

• 5374-06-1 4,6-di-tert-butylresorcinol 
• 3433-80-5 1-Bromo-2-bromomethyl-benzene 

Relevant articles and documents

Direct transition-metal-free intramolecular arylation of phenols

(Chemical Equation Presented) Direct transition-metal-free, base-mediated intramolecular arylation of phenols with aryl halides has been developed. In the presence of 2.5 equiv of t-BuOK in dioxane at 140 °C, the intramolecular cyclization of 3-(2-halobenzyloxy)phenols affords 6H-benzo[c]chromenes in high yields. This reaction proceeds by an initial formation of a benzyne intermediate followed by an aromatic sp2 C-H functionalization (a formal C-H activation) to form the carbon-carbon bond.