106860-70-2Relevant academic research and scientific papers
REACTION OF ELECTROGENERATED 2-NITROSOBENZOIC ACIDS WITH SULPHINIC ACIDS. A CONVENIENT ROUTE TO N-SULFONYLBENZISOXAZOLONES
Gault, C.,Moinet, C.
, p. 3429 - 3436 (2007/10/02)
A one-pot synthesis of N-sulfonylbenzisoxazolones from 2-nitrobenzoic acids and sulphinic acids is described; it successively involves: - electrosynthesis, in a cell with two consecutive porous electrodes of opposite polarities, of the sodium salt of nitr
Preparation electrochimique de nitrosobenzenes
Lamoureux, Catherine,Moinet, Claude
, p. 59 - 66 (2007/10/02)
The electrosynthesis of nitrosobenzenes from the corresponding nitro compounds occurs in a "redox" electrolysis cell with flowing solution through two consecutive porous working electrodes of opposite polarities; the nitro compound is reduced at the first porous electrode (cathode) and the resulting phenylhydroxylamine is totally oxidized into the nitroso derivate at the second porous electrode (anode).Some examples show the preparation of nitroso derivatives which are soluble in buffered aqueous medium or in alcohol-water medium.
