1068655-96-8Relevant academic research and scientific papers
Highly enantioselective syntheses of functionalized α-methylene-γ-butyrolactones via Rh(I)-catalyzed intramolecular Alder ene reaction: Application to formal synthesis of (+)-pilocarpine
Lei, Aiwen,He, Minsheng,Zhang, Xumu
, p. 8198 - 8199 (2002)
A highly enantioselective Rh(I)-catalyzed intramolecular Alder ene reaction has been developed. The desired products, 3-vinyl, vinyl acetate, and vinyl ether-substitued α-methylene-γ-butyrolactones were formed in high yields. Aldehydes were produced with
