106880-66-4

Basic information

• Product Name: 1,2,3,6-tetra-O-benzoyl-4-deoxy-4-iodo-α-D-glucopyranose
• CAS NO: 106880-66-4
• Molecular Weight: 706.487
• Mol File: 106880-66-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1,2,3,6-tetra-O-benzoyl-4-deoxy-4-iodo-α-D-glucopyranose(CAS DataBase Reference)
• NIST Chemistry Reference: 1,2,3,6-tetra-O-benzoyl-4-deoxy-4-iodo-α-D-glucopyranose(106880-66-4)
• EPA Substance Registry System: 1,2,3,6-tetra-O-benzoyl-4-deoxy-4-iodo-α-D-glucopyranose(106880-66-4)

Safety Data

• Hazardous Substances Data: 106880-66-4(Hazardous Substances Data)

Upstream product

• 114718-46-6 1,2,3,6-tetra-O-benzoyl-α-D-galactopyranose 
• 98-88-4 benzoyl chloride 

Downstream Products

• 151073-09-5 1,2,3,6-tetra-O-benzoyl-4-deoxy-α-D-xylo-hexopyranose 
• 106880-67-5 1,3,6-tri-O-benzoyl-2,4-dideoxy-α-D-threo-hexopyranose 

Relevant articles and documents

Synthesis of modified aldonic acids and studies of their substrate efficiency for dihydroxy acid dehydratase (DHAD)

Modified aldopentonic and aldohexonic acids were synthesized in order to study the electronic requirements for a successful enzymatic conversion into their corresponding 2-keto 3-deoxy analogues by dihydroxy acid dehydratase (DHAD), an enzyme from the biosynthetic pathway of branched chain amino acids. Analytical tests with the novel artificial substrates (18)-(21) and (27) provided evidence that the amount of conversion could be enhanced by replacement of the hydroxy group at C 4 of L-arabinonic acid (21) with less electron-withdrawing, ambivalent or electron-donating substituents. Modified aldohexonic acids were no substrates for DHAD, perhaps due to less perfect binding to the active site presumably for steric reasons. For 4-deoxy-L-threo-pentonic acid (18) the enzymatic conversion into 3,4-dideoxy-2-ketopentonic acid (29) by DHAD could be achieved on a preparative scale.