1069130-73-9Relevant articles and documents
Transition metals in organic synthesis. Part 101: Convergent total synthesis of 1,6-dioxygenated carbazole alkaloids
B?rger, Carsten,Kn?lker, Hans-Joachim
, p. 6727 - 6736 (2012/09/05)
Using a palladium(II)-catalysed oxidative cyclisation as key step, we describe a highly efficient total synthesis of a series of naturally occurring 1,6-dioxygenated carbazole alkaloids: clausenine, 6-methoxymurrayanine, clausenol, clausine G, clausine I, clausine Z and methyl 1,6-dihydroxy-9H- carbazole-3-carboxylate.
Transition metals in organic synthesis, Part 85.1 A general approach to 1,6-dioxygenated carbazole alkaloids - first total synthesis of clausine G, clausine I, and clausine Z
B?rger, Carsten,Kn?lker, Hans-Joachim
body text, p. 1698 - 1702 (2009/05/07)
Using the palladium-catalyzed construction of the carbazole framework, a highly efficient route to 1,6-dioxygenated carbazole alkaloids has been developed and applied to the total synthesis of clausenine, 6- methoxymurrayanine, clausenol, clausine G, clausine I, and clausine Z. The three latter natural products have been synthesized for the first time. Thieme Stuttgart.
