106915-94-0Relevant academic research and scientific papers
SYNTHESE, PROPRIETES COMPLEXANTES ET POUVOIR EXTRACTANT DE β-DIPHOSPHORAMIDES HYDROPHOBES
Ladeveze, G. Doucet,Azad, Y. Jabbari,Rodehueser, L.,Rubini, P.,Selve, C.,Delpuech, J. J.
, p. 371 - 384 (1986)
New hydrophobic β-diphosphoramides of the type 2NR where R = hexyl(OHIPA), dodecyl(ODIPA) or benzyl(OBIPA) have been synthesized; their hydrophobic character and their complexing and extracting abilities have been measured and compared to those of NIPA (R = methyl).It is shown that, amoung the four ligands, the compound ODIPA presents the best extracting properties because of its insolubility in water and its important complexing ability.
N,N-N',N'OCTAMETHYLIMIDODIPHOSPHO-TETRAMIDE - REEXAMEN DE LA SYNTHESE ET ETUDE DE LA REACTIVITE COMME NUCLEOPHILE
Delpuech, J. J.,Fasan, G.,Rodehueser, L.,Rubini, P.,Selve, C.
, p. 281 - 290 (2007/10/02)
An efficient synthetic pathway of N,N-N',N'Octamethylimidodiphosphotetramide was realised by modifying a procedure described in the literature and by improving it in the light of the properties of the product.The nucleophilic properties of the imidic nitrogen (under its anionic form) are much less pronounced than those of phthalimide (Gabriel's reagent), of similar structure.
