59950-71-9

Upstream product

• 1605-65-8 N,N,N',N'-Tetramethylphosphorodiamidic chloride 
• 100-46-9 benzylamine 

Downstream Products

• 98056-35-0 N-allyl-N-benzyl bis-dimethylphosphoric triamide 
• 1035793-69-1 N-benzyl N-propargyl bis-dimethylphosphoramide 
• 59950-93-5 N-benzyl N-propargylbis-dimethylphosphoramide 
• 75858-54-7 N'-Benzyl-N,N-dimethyl-but-2-yne-1,4-diamine 
• 75858-47-8 C₁₇H₂₉N₄OP 
• 1197-51-9 N-propargylbenzylamine 
• 4383-22-6 Allylbenzylamine 
• 100-52-7 benzaldehyde 
• 4720-29-0 3-(benzylamino)propan-1-ol 
• 98056-41-8 bis-dimethylphosphoramide de N-benzyle et de N-(hydroxy-3 propyle) 
• 106915-94-0 N,N,N',N' octamethyl, N'' benzylimido diphosphoramide 

Relevant academic research and scientific papers

Thermal Oxidative Deamination of Aliphatic Amines to Aldehydes with Bis(diphenylphosphinyl) Peroxide

Reaction of N-substituted alkylamines having pseudoacidic hydrogen at the 1-methylene group with bis(diphenylphosphinyl) peroxide yields the deaminated products by thermal elimination of diphenylphosphinic acid from the intermediate O-diphenylphosphinylhydroxylamines.

SYNTHESE, PROPRIETES COMPLEXANTES ET POUVOIR EXTRACTANT DE β-DIPHOSPHORAMIDES HYDROPHOBES

New hydrophobic β-diphosphoramides of the type 2NR where R = hexyl(OHIPA), dodecyl(ODIPA) or benzyl(OBIPA) have been synthesized; their hydrophobic character and their complexing and extracting abilities have been measured and compared to those of NIPA (R = methyl).It is shown that, amoung the four ligands, the compound ODIPA presents the best extracting properties because of its insolubility in water and its important complexing ability.

HYDROBORATION D'AMINES INSATUREES. XI.REGIO- ET STEREOSELECTIVITE DES HYDRURES DU BORE VIS A VIS D'AMINES PROPARGYLIQUES N-PHOSPHORYLEES

The regioselectivity and the stereoselectivity of the hydroboration of N-alkylallylphosphoramide was examined.This study shows the preferential formation of γ-boron derivatives (90 to 100percent) and the excellent stereospecificity of the reaction (100percent (Z) configuration).The PIV-N bond hinders the nitrogen-boron coordination which is responsible for the anomalous behavior of N-propargylic amines towards hydroboration and allows the same regio- and stereo-selectivity as for alkynes.The iodination of boron derivatives leads, with good yields, to N-phosphoryl-β-ethylenic amines.

HYDROBORATION OF UNSATURATED AMINES VIII A CONVENIENT SYNTHESIS OF AMINO-3 PROPANOL-1

A new route with increased yield and stereoselectivity is reported for the synthesis of amino-3 propanols-1.It involved a hydroboration-oxidation reaction using bora- 9 bicyclo nonane.The amino group was protected by a phosphorylated grouping giving rise to novel and potentially useful phosphorylated reagents.

Aminomethylation of N-propargylphosphoramides. Synthesis of unsymmetrical acetylenic diamines

The preparation of N-alkyl-N-(4-dialkylamino-2-butylnyl)phosphoramides 3 using the Mannich reaction is described.The acidic hydrolysis of those phosphoramides leads to unsymmetrical acetylenic diamines 4.