106924-77-0Relevant academic research and scientific papers
GENERATION AND ALKYLATION REACTION OF 1-BROMOALKENYLZINCATE
Harada, Toshiro,Hara, Daiji,Hattori, Kazuhiro,Oku, Akira
, p. 3821 - 3824 (1988)
1-Bromoalkenylzincates (R1R2C=CBrZnR32Li) which are generated by the reaction of 1,1-dibromoalkenes with a lithium triorganozincate (R33ZnLi) at -85 deg C undergo alkylation reaction at temperatures from -85 deg C to 0 deg C to give alkenes R1R2C=CHR3.
Stereoselective Synthesis of (E)- and (Z)-Disubstituted Vinyl Bromides via Organoboranes
Brown, Herbert C.,Bhat, N. G.,Rajagopalan, Shyamala
, p. 480 - 482 (2007/10/02)
Treatment of - and -disubstituted vinyldimethoxyboranes, prepared as described previously, with bromine, followed by a base, produced - and -disubstituted vinyl bromides in good yields (61-80percent) and excellent stereochemical purities (>/-97percent).In both cases, replacement of the boron moiety with bromine proceeds with inversion.
