GENERATION AND ALKYLATION REACTION OF 1-BROMOALKENYLZINCATE

DOI: 10.1016/S0040-4039(00)82124-3

Source and publish data:

Tetrahedron Letters p. 3821 - 3824 (1988)

Update date:2022-08-04

Topics:

Authors:

Harada, Toshiro

Hara, Daiji

Hattori, Kazuhiro

Oku, Akira

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Article abstract of DOI:10.1016/S0040-4039(00)82124-3

1-Bromoalkenylzincates (R¹R²C=CBrZnR³₂Li) which are generated by the reaction of 1,1-dibromoalkenes with a lithium triorganozincate (R³₃ZnLi) at -85 deg C undergo alkylation reaction at temperatures from -85 deg C to 0 deg C to give alkenes R¹R²C=CHR³.

Full text of DOI:10.1016/S0040-4039(00)82124-3

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