106924-78-1Relevant academic research and scientific papers
Stereoselective Synthesis of (E)- and (Z)-Disubstituted Vinyl Bromides via Organoboranes
Brown, Herbert C.,Bhat, N. G.,Rajagopalan, Shyamala
, p. 480 - 482 (1986)
Treatment of - and -disubstituted vinyldimethoxyboranes, prepared as described previously, with bromine, followed by a base, produced - and -disubstituted vinyl bromides in good yields (61-80percent) and excellent stereochemical purities (>/-97percent).In both cases, replacement of the boron moiety with bromine proceeds with inversion.
