106925-00-2Relevant academic research and scientific papers
A NOVEL REACTION OF 1-PHOSPHONYLOXY-F-1-ALKENEPHOSPHONATES: HIGHLY EFFECTIVE METHOD FOR THE SYNTHESIS OF α,β-UNSATURATED F-CARBOXYLIC ACID DERIVATIVES
Ishihara, Takashi,Yamasaki, Yasuhiro,Ando, Teiichi
, p. 2879 - 2880 (1986)
1-Phosphonyloxy-F-1-alkenephosphonates, easily prepared from F-alkanoic acid chlorides and triethyl phosphite, undergo a unique fluoride ion-catalyzed reaction with primary and secondary amines or alcohols to afford the corresponding α,β-unsaturated F-carboxylic acid derivatives in excellent yields, along with diethyl fluorophosphate and phosphite.
