106929-10-6

Upstream product

• 138629-16-0 Methanesulfonic acid 2-((1S,2R,3S,4R,5R)-3,4-bis-benzyloxy-6,8-dioxa-bicyclo[3.2.1]oct-2-yl)-ethyl ester 
• 138607-73-5 (E)-3-((1S,2R,3S,4R,5R)-3,4-Bis-benzyloxy-6,8-dioxa-bicyclo[3.2.1]oct-2-yl)-acrylic acid methyl ester 
• 110316-62-6 (E)-3-((1S,2R,3S,4R,5R)-3,4-Bis-benzyloxy-6,8-dioxa-bicyclo[3.2.1]oct-2-yl)-prop-2-en-1-ol 
• 138629-17-1 (1S,2R,3S,4R,5R)-3,4-Bis-benzyloxy-2-(2-iodo-ethyl)-6,8-dioxa-bicyclo[3.2.1]octane 
• 138629-15-9 2-((1S,2R,3S,4R,5R)-3,4-Bis-benzyloxy-6,8-dioxa-bicyclo[3.2.1]oct-2-yl)-ethanol 
• 138607-71-3 (1S,2R,3S,4R,5R)-3,4-Bis-benzyloxy-2-vinyl-6,8-dioxa-bicyclo[3.2.1]octane 
• 138607-46-2 (1S,2R,3S,4R,5R)-2-Allyl-3,4-bis-benzyloxy-6,8-dioxa-bicyclo[3.2.1]octane 
• 138607-72-4 ((1S,2R,3S,4R,5R)-3,4-Bis-benzyloxy-6,8-dioxa-bicyclo[3.2.1]oct-2-yl)-methanol 
• 121964-07-6 2,3-di-O-benzyl-4,5-O-isopropylidene-D-arabinitol 
• 74878-90-3 Toluene-4-sulfonic acid (1S,2S,3S,4R,5R)-2-allyl-3-hydroxy-6,8-dioxa-bicyclo[3.2.1]oct-4-yl ester 
• 100-39-0 benzyl bromide 
• 106929-09-3 (2S,3R,4R)-2,3-dibenzyloxy-4,5-isopropylidenedioxypentanal 

Downstream Products

• 106929-11-7 (2R,3R,4R,5R)-4,5-Bis-benzyloxy-1-((1S,2R,3S,4R,5R)-3,4-bis-benzyloxy-6,8-dioxa-bicyclo[3.2.1]oct-2-yl)-5-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-pentane-2,3-diol 
• 106974-26-9 (2S,3S,4R,5R)-4,5-Bis-benzyloxy-1-((1S,2R,3S,4R,5R)-3,4-bis-benzyloxy-6,8-dioxa-bicyclo[3.2.1]oct-2-yl)-5-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-pentane-2,3-diol 
• 106974-27-0 Benzoic acid (2R,3R,4R,5S,6S)-3,4-bis-benzyloxy-6-((1S,2R,3S,4R,5R)-3,4-bis-benzyloxy-6,8-dioxa-bicyclo[3.2.1]oct-2-ylmethyl)-5-hydroxy-tetrahydro-pyran-2-ylmethyl ester 

Relevant academic research and scientific papers

Preferred Conformation of C-Glycosides. 8. Synthesis of 1,4-Linked Carbon Disaccharides

Three general synthetic routes to 1,4-linked carbon disaccharides (e.g., 3, 4, 15-17, 21-23, 44, and 45) are presented.Control of the stereochemistry at C.1', C.2', C.5'and C.4, the incorporation of deuterium labels at the C.α position, and structural mod

Synthesis of C-Disaccharides

Stereocontrolled syntheses of four C-disaccharides 10, 11, 16, and 17 were reported.The (n-Pr)3SiH/BF3*Et2O reduction of hemiketals such as 7 yielded the equatorially substituted C-glycoside as the major product while C-alkylation (CHCCH2Si(CH3)3/BF3*E