106986-27-0

Basic information

• Product Name: 1'-methyl-3'-phenyl-2'-propen-1'-yl (1'R,2R/2S)-(E)-N-benzoyl-C-phenylglycinate
• CAS NO: 106986-27-0
• Molecular Weight: 385.463
• Mol File: 106986-27-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1'-methyl-3'-phenyl-2'-propen-1'-yl (1'R,2R/2S)-(E)-N-benzoyl-C-phenylglycinate(CAS DataBase Reference)
• NIST Chemistry Reference: 1'-methyl-3'-phenyl-2'-propen-1'-yl (1'R,2R/2S)-(E)-N-benzoyl-C-phenylglycinate(106986-27-0)
• EPA Substance Registry System: 1'-methyl-3'-phenyl-2'-propen-1'-yl (1'R,2R/2S)-(E)-N-benzoyl-C-phenylglycinate(106986-27-0)

Safety Data

• Hazardous Substances Data: 106986-27-0(Hazardous Substances Data)

Upstream product

• 119817-55-9 methyl 2-benzoylamino-2-phenyl-acetate 
• 62413-47-2 (2R,3E)-4-phenyl-3-buten-2-ol 
• 5876-76-6 (R)-4-phenylbut-3-yn-2-ol 
• 106985-89-1 Benzoylamino-phenyl-acetic acid (S)-1-methyl-3-phenyl-prop-2-ynyl ester 
• 2900-27-8 2-(tert-butoxycarbonylamino)-2-phenylacetic acid 
• 98-88-4 benzoyl chloride 

Downstream Products

• 106986-14-5 (1'S,2R/2S)-2,4-diphenyl-2-(1'-methyl-3'-phenyl-1'-propyl)-3-oxazolin-5-one 
• 106986-16-7 (R)-1,4-diphenyl-2-methylbutan-1-one 
• 106986-18-9 (2R),(E/Z)-1,4-diphenyl-2-methylbutan-1-one oxime 
• 106986-14-5 (1'R,2R/2S)-2,4-diphenyl-2-(1'-methyl-3'-phenyl-1'-propyl)-3-oxazolin-5-one 
• 106986-22-5 (2R,2'S),(E/Z)-O-<2'-methoxy-2'-(trifluoromethyl)phenylacetyl>-1,4-diphenyl-2-methylbutan-1-one oxime 
• 106986-22-5 (2S,2'S),(E/Z)-O-<2'-methoxy-2'-(trifluoromethyl)phenylacetyl>-1,4-diphenyl-2-methylbutan-1-one oxime 
• 106986-29-2 (1'R,2R/2S)-(E)-2,4-diphenyl-2-(1'-methyl-3'-phenyl-2'-propen-1'-yl)-3-oxazolin-5-one 
• 106986-29-2 (1'S,2R/2S)-(E)-2,4-diphenyl-2-(1'-methyl-3'-phenyl-2'-propen-1'-yl)-3-oxazolin-5-one 

Relevant articles and documents

STEREOCHEMISTRY OF -SIGMATROPIC REARRANGEMENTS IN THE OXAZOLE SERIES

The transfer of chirality from optically active propargyl and cinnamyl N-acyl-C-phenylglycinates to α-branched ketones may be achieved by sigmatropic rearrangements of oxazole intermediates followed by catalytic hydrogenation of the resulting 3-oxazolinones and subsequent reductive ring cleavage.From (R)-4-phenyl-3-buten-1-ol both enantiomers of 1,4-diphenyl-2-methylbutan-1-one (6) could be obtained by sarting either from the (E)- or (Z)-diastereomer of the alcohol.