106991-85-9Relevant academic research and scientific papers
Synthesis of Thioethers Using Triethylamine-Activated Phosphorus Decasulfide (P410
Turkoglu, Gulsen,Cinar, M. Emin,Ozturk, Turan
, p. 3618 - 3624 (2016)
The synthesis of thioethers in excellent yields was achieved under mild conditions via the displacement reaction of halogens by sulfur. The cross-reaction of 2-(α-bromoacetyl)thiophene with triethylamine-activated phosphorus decasulfide (Et3N-P2S5) was elaborated by utilizing DFT calculations.
Synthesis of oxathiane and morpholine from acyclic precursors: A modified Mitsunobu reaction
Paul, Nidhin,Kaladevi, Selvam,Beneto, Arockiam Jesin,Muthusubramanian, Shanmugam,Bhuvanesh, Nattamai
scheme or table, p. 6892 - 6901 (2012/09/11)
Synthesis of a set of isomeric 2,4,6-triarylmorpholines and 2,6-diaryloxathianes from the corresponding 1,5-diols has been described. The method provides an efficient route to six-membered heterocycles from acyclic diols and is found to be better than Mitsunobu procedure in yield and waste management. In a related study, the ring contraction of pyranone to two isomeric cyclopentenone derivatives through Nazarov reaction has been noticed.
Preparation of 3,6-Disubstituted Pyridazines from 3-Thiapentane-1,5-diones via 2,7-Dihydro-1,4,5-thiadiazepines
Nakayama, Juzo,Konishi, Toru,Ishii, Akihiko,Hoshino, Masamatsu
, p. 2608 - 2612 (2007/10/02)
A series of 3-thiapentane-1,5-diones condense with hydrazine in the presence of a catalytic amount of p-toluenesulfonic acid in refluxing ethanol to give 2,7-dihydro-1,4,5-thiadiazepines in excellent yields.Thermal decomposition of the latter compounds in
