1070-91-3

Basic information

• Product Name: bis(trimethyltin) sulfide
• Synonyms: bis(trimethyltin) sulfide;Bis(trimethylstannyl) sulfide;Hexamethyldistannathiane;Thiobis(trimethylstannane);Thiobis(trimethyltin);Trimethyltin sulfide;Hexamethyldistannathione
• CAS NO: 1070-91-3
• Molecular Formula: C₆H₁₈SSn₂
• Molecular Weight: 359.69
• Mol File: 1070-91-3.mol
• Article Data: 3

Chemical Properties

• Melting Point: 6 °C
• Boiling Point: °Cat760mmHg
• Flash Point: °C
• Appearance: /
• Density: 1.632
• CAS DataBase Reference: bis(trimethyltin) sulfide(CAS DataBase Reference)
• NIST Chemistry Reference: bis(trimethyltin) sulfide(1070-91-3)
• EPA Substance Registry System: bis(trimethyltin) sulfide(1070-91-3)

Safety Data

• Hazard Codes: T+,N
• Statements: 26/27/28-50/53
• Safety Statements: 26-27-28-45-60-61
• RIDADR: 2788
• HazardClass: 6.1(b)
• PackingGroup: III
• Hazardous Substances Data: 1070-91-3(Hazardous Substances Data)

Usage

InChI:InChI=1/6CH3.H2S.2Sn/h6*1H3;1H2;;/q;;;;;;;;+1/p-1/r2C3H9Sn.H2S/c2*1-4(2)3;/h2*1-3H3;1H2/q;+1;/p-1

Upstream product

• 16892-64-1 2,2,4,4,6,6-hexamethyl-1,3,5,2,4,6-trithiatristanninane 
• 12775-96-1 copper 
• 124300-96-5 N,N,N'-tris(trimethylstannyl)1,1-dimethylethane sulfine imideamide 
• 55526-04-0 (CH₃)3SnB{N(CH₃)2}2 
• 7704-34-9 sulfur 
• 1068-67-3 bis(trimethylstannyl)methylamine 
• 165334-37-2 2,3-dimethyl-3-triphenylphosphonio-2-silabutane-2-thiolate 

Downstream Products

• 90690-15-6 2,4,5-triphenyl-2-thioxo-1,3,2λ⁵,4,5-dithiatriphospholane 
• 1066-45-1 trimethyltin(IV)chloride 
• 7440-31-5 tin 
• 594-27-4 tetramethylstannane 
• 2273-45-2 dimethyltin oxide 
• 25070-46-6 tetraphosphorus nonasulfide 
• 811-73-4 trimethylstannyl iodide 
• 16892-64-1 2,2,4,4,6,6-hexamethyl-1,3,5,2,4,6-trithiatristanninane 
• 27484-94-2 (CH₃)2BSB(CH₃)2 
• 1066-44-0 trimethyltin bromide 
• 31732-45-3 trimethylstannyl dimethylboryl sulfane 
• 19962-43-7 (CH₃)3SnCH₂C₆H₄-m-CH₃ 
• 940-00-1 (4-methoxyphenyl)trimethylstannane 
• 17113-77-8 2-trimethylstannylanisole 

Relevant articles and documents

Heteroorganic betaines 3. * Reactions of betaines containing the +P-C-Si-S- fragment

The [Ph3P+-CMe2-SiMe2-SEt]Br- salt was prepared by the reaction of betaine Ph3P+-CMe2SiMeR-S- (1a: R = Me) with EtBr. Acetylation of betaine 1a or Et3P+-CHMeSiMe2-S- (2a) afforded 2,2,6-trimethyl-1,3-dioxa-2-silacyclohex-5-ene-4-thione Me2SiOC(=S)CH=C(Me)O or the [Et3P+-CHMeSiMe2Cl]Cl- salt depending on the reagent ratio. The reactions of betaines 1a,b (1b: R = Ph) or 2 with compounds (R3Sn)2X (X = O or NMe) can be used for the generation of silanones [RMeSi=O] and silaneimines [RMeSi=NMe] in solutions. The reactivity of betaines Ph3P+-CHR1SiMeR2-S- (R1 = H or Me and R2 = Me or Ph) is determined by the equilibrium between the zwitterionic and ylide Ph3P=CR1SiMeR2SH tautomers that exist in solutions.

Metall-Bor-Verbindungen, 13. Zur Synthese und Reaktivitaet einiger (Trimethylstannyl)borane

The preparation of some amino(trimethylstannyl)boranes and their chemical properties are described.With Me3SnLi (Me = CH3) as a reagent only the synthesis of Me3SnB(NR2)2 (1a, b), Me3SnBCl(NR2) (2a, b), and (Me3Sn)2BNR2 (3b) was achieved.The stannylboranes Me3SnB(NR2)2 show astonishing thermal stability.Their Sn - B bonds are broken by hydrogen, the halogens, and chalcogens as well as by alcohols.HCl cleaves the B - N bond.