17113-78-9

Basic information

• Product Name: 1-Methoxy-3-(trimethylstannyl)benzene
• Synonyms: (m-Methoxyphenyl)trimethylstannane;1-(Trimethylstannyl)-3-methoxybenzene;1-Methoxy-3-(trimethylstannyl)benzene
• CAS NO: 17113-78-9
• Molecular Formula: C₁₀H₁₆OSn
• Molecular Weight: 270.94
• Mol File: 17113-78-9.mol
• Article Data: 6

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 1-Methoxy-3-(trimethylstannyl)benzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-Methoxy-3-(trimethylstannyl)benzene(17113-78-9)
• EPA Substance Registry System: 1-Methoxy-3-(trimethylstannyl)benzene(17113-78-9)

Safety Data

• Hazardous Substances Data: 17113-78-9(Hazardous Substances Data)

Upstream product

• 2398-37-0 3-methoxyphenyl bromide 
• 1066-45-1 trimethyltin(IV)chloride 
• 1070-91-3 bis(trimethyltin) sulfide 
• 100-66-3 methoxybenzene 
• 661-69-8 hexamethyldistannane 
• 536-90-3 m-Anisidine 
• 766-85-8 3-methoxy-1-iodobenzene 
• 1066-44-0 trimethyltin bromide 
• 36282-40-3 (3-methoxyphenyl)magnesium bromide 
• 13538-32-4 O,O-diethyl O-3-methoxyphenyl phosphate 
• 16643-09-7 trimethylstannyl sodium 

Downstream Products

• 1066-45-1 trimethyltin(IV)chloride 
• 1379449-85-0 C₃₃H₃₇NO₆ 
• 6136-67-0 3-methoxybenzophenone 
• 2113-56-6 3-methoxybiphenyl 
• 10130-74-2 m-Methoxybenzenesulfonyl chloride 
• 91612-04-3 N-(3-Chlorophenyl)-3-methoxybenzamide 
• 93087-50-4 1-methoxy-3-(phenylsulfonyl)benzene 
• 6833-23-4 3-methoxy-N-phenylbenzamide 
• 119100-84-4 2-(3-Methoxy-phenyl)-4-methyl-nicotinic acid ethyl ester 

Relevant articles and documents

Visible-Light-Driven Synthesis of Arylstannanes from Arylazo Sulfones

The visible-light-driven preparation of (hetero)aryl stannanes was carried out under both photocatalyst- and metal-free conditions via irradiation of arylazo sulfones in the presence of hexaalkyldistannanes. The reaction shows a high efficiency and a wide substrates scope. The resulting crude organotin derivatives can be directly employed in a Stille protocol.

1,2,3,4-TETRAHYDRO-QUINOLINE DERIVATIVES AS CETP INHIBITORS

The invention is directed to compounds of Formula (I) described herein useful as CETP inhibitors, compositions containing them, and methods of using them.

Synthesis of Aromatic and Olefinic Sodium Sulfonates by Electrophilic Destannylation with Trimethylsilyl Chlorosulfonate

A mild and effective method for the preparation of a variety of aromatic, olefinic, and acetylenic sodium sulfonates is described.The reaction of trialkylaryl- (2a-k) and -heteroarylstannanes (4a-d), bis-(1-alkenyl)dibutylstannanes (6a-f), or trialkylakynylstannanes with trimethylsilyl chlorosulfonate (1) followed by hydrolysis with aqueous NaHCO3 provides the sodium sulfonates in an ipso-specific and in the case of vinylic stannanes stereospecific manner.A comparision of the reactivity of stannylated and silylated olefinic compounds 13 and 14 underlines the greater leaving ability of the stannyl moiety.The in situ preparation of the stannanes makes it possible to apply the synthetic method to natural products such as N-substituted apocodeine (17). - Key Words: Electrophilic aromatic substitution/ Electrophilic vinylic substitution/ Trialkylstannanes, application of/ Arylsulfonates, sodium salts of/ Vinylsulfonates, sodium salts of