107089-00-9Relevant academic research and scientific papers
Benzyl radical addition reaction through the homolytic cleavage of a benzylic C-H bond
Ueda, Masafumi,Kondoh, Eiko,Ito, Yuta,Shono, Hiroko,Kakiuchi, Maiko,Ichii, Yuki,Kimura, Takahiro,Miyoshi, Tetsuya,Naito, Takeaki,Miyata, Okiko
supporting information; experimental part, p. 2062 - 2064 (2011/05/08)
Direct generation of a benzyl radical by C-H bond activation of toluenes and the addition reaction of the resulting radical to an electron deficient olefin were developed. The reaction of dimethyl fumarate with toluene in the presence of Et3B as a radical initiator at reflux afforded 2-benzylsuccinic acid dimethyl ester in good yield.
PREPARATION OF (R)-VERATRYL- AND (R)-(3-METHOXYBENZYL)SUCCINATES
Barnier, Jean-Pierre,Blanco, Luis,Guibe-Jampel, Eryka,Rousseau, Gerard
, p. 5051 - 5058 (2007/10/02)
LP-catalyzed hydrolyses of 4-cyanomethyl 1-methyl veratryl- and (3-methoxy benzyl)succinates lead in high optical yield to the corresponding (R)-butanoic acids.HLE-catalyzed hydrolyses of various methyl and cyanomethyl veratrylsuccinates lead to mixtures
Studies on the constituents of Jatropha gossypifolia Linn: Synthesis of prasanthaline, a new lignan, and isolation of dihydroprasanthaline
Banerji, J.,Bose, P.,Das, B.
, p. 711 - 713 (2007/10/02)
Prasanthaline (1), a new lignan isolated by Chatterjee et al. , has been synthesised by two routes.In the first appraoch naturally occurring suchilactone (2) on LAH reduction followed by acetylation affords 1, identical wit
LE TETRAKIS(TRIFLUOROACETATE) DE RUTHENIUM(IV), NOUVEAU CATALYSEUR A TEMPERATURE AMBIANTE DU COUPLAGE BIARYLIQUE OXIDANT NON PHENOLIQUE-PREMIERE SYNTHESE TOTALE BIOMIMETIQUE DU NEOISOSTEGANE-
Landais, Y.,Robin, J.-P.
, p. 1785 - 1788 (2007/10/02)
In situ generated Ruthenium(IV) tetrakis(trifluoroacetate) -a new organometallic reagent- was used in intramolecular non-phenolic oxydative biaryl coupling of dibenzylbutanolides, and an application to the first total synthesis of neoisostegane was perfor
