1070970-82-9Relevant academic research and scientific papers
New synthetic approach to α-fluoro-β-arylvinyl sulfones and their application in Diels-Alder reactions
Shastin, Aleksey V.,Nenajdenko, Valentine G.,Muzalevskiy, Vasiliy M.,Balenkova, Elizabeth S.,Fr?hlich, Roland,Haufe, Günter
, p. 9725 - 9732 (2008/12/22)
A new pathway towards α-fluoro-β-arylvinyl sulfones was elaborated. The reaction of β-bromo-β-fluorostyrenes with sodium 4-methylphenylsulfinate proceeds with maximum 94:6 stereoselectivity and 72-90% yields. The formed α-fluoro-β-arylvinyl sulfones were
