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Reactions with Aziridines, 41. - Highly Regioselective (Abnormal) Ring Opening of 1-Benzoyl-2,2-dimethylaziridine by Simple Nitrile Anions
Assithianakis, Petros,Stamm, Helmut
, p. 855 - 858 (2007/10/02)
The anions 3a-e of the acetonitriles 2a-e cleave the aziridine ring of 1-benzoyl-2,2-dimethylaziridine (1) at the tertiary C-atom (abnormal opening) and provide in this way good yields of the 4-(benzoylamino)-3,3-dimethylbutyronitriles 5a-e and of the 2-(benzoylimino)pyrrolidine 7a, respectively.Positional isomers could not be detected.
