107148-38-9Relevant academic research and scientific papers
Sterically directed iridium-catalyzed hydrosilylation of alkenes in the presence of alkynes
Muchnij, Jill A.,Kwaramba, Farai B.,Rahaim, Ronald J.
supporting information, p. 1330 - 1333 (2014/04/03)
A selective iridium catalyzed hydrosilylation of alkenes in the presence of more reactive alkynes is described. By utilizing [IrCl(COD)]2 in the presence of excess COD, hydrosilylation of alkenes and alkynes with ethynylsilanes is achieved with
Construction of terminal conjugated enynes: Cu-mediated cross-coupling reaction of alkenyldialkylborane with (trimethylsilyl)ethynyl bromide
Hoshi, Masayuki,Kawamura, Noritsugu,Shirakawa, Kazuya
, p. 1961 - 1970 (2007/10/03)
The cross-coupling reaction of (E)- and (Z)-alk-1-enyldialkylborane with (trimethylsilyl)ethynyl bromide proceeds in the presence of a catalytic amount of copper(II) acetylacetonate and a base under extremely mild conditions to provide conjugated enynes w
Construction of terminal conjugated enynes: Regio- and stereoselective syntheses of 3-alken-1-ynes and 1-trimethylsilyl-3-alken-1-ynes from alkenyldialkylboranes and (trimethylsilyl)ethynyl bromide
Hoshi, Masayuki,Shirakawa, Kazuya
, p. 1101 - 1104 (2007/10/03)
The cross-coupling reaction of (E)- and (Z)-1-alkenyldialkylboranes with (trimethylsilyl)ethynyl bromide proceeds in the presence of a base and a catalytic amount of Cu(acac)2 under very mild conditions to provide conjugated enynes whose carbon
