1072-77-1

Basic information

• Product Name: Bicyclo[3.2.0]hept-6-en-2-one
• CAS NO: 1072-77-1
• Molecular Formula: C7H8O
• Molecular Weight: 108.14
• Mol File: 1072-77-1.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Bicyclo[3.2.0]hept-6-en-2-one(CAS DataBase Reference)
• NIST Chemistry Reference: Bicyclo[3.2.0]hept-6-en-2-one(1072-77-1)
• EPA Substance Registry System: Bicyclo[3.2.0]hept-6-en-2-one(1072-77-1)

Safety Data

• Hazardous Substances Data: 1072-77-1(Hazardous Substances Data)

Downstream Products

• 98877-49-7 3-(phenylsulfinyl)bicyclo<3.2.0>hept-en-2-one 
• 124447-25-2 3-Phenylsulfanyl-bicyclo[3.2.0]hept-6-en-2-one 
• 1901-34-4 cyclohepta-2,4-dienone 
• 124469-30-3 C₁₃H₁₁⁽²⁾HO₂S 
• 98877-51-1 bicyclo<3.2.0>hepta-3,6-dien-2-one tosylohydrazone 
• 98877-50-0 3-(phenylsulfinyl)bicyclo<3.2.0>hept-en-2-one tosylhydrazone 
• 80534-52-7 4-Phenylsulfanyl-tricyclo[4.1.0.0^2,7]heptan-3-one 
• 80534-53-8 Acetic acid 3-oxo-4-phenylsulfanyl-tricyclo[4.1.0.0^2,7]hept-4-yl ester 

Relevant articles and documents

σ-bishomoaromatic heterocycles: Reactivity and synthesis of 3-oxatetracyclo[3.3.0.02,804,6]octane by photolysis at 185 nm

The title compound 5 was produced by 185 nm photolysis of 8. The products of the 185 run photolysis can be rationalized by the assumption of the two diradical intermediates 16 and 17. At a temperature between 150 and 200°C 5 reacts with fumaronitrile 23 to give the adducts 7 and 26 in a ratio of about (5 : 1). The kinetic analysis of this reaction shows, that the adduct 7 is formed by 1,3 dipolar cycloaddition of intermediate carbonyl ylide 6.