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Bicyclo[3.2.0]hept-6-en-2-one, also known as norbornenone or norcamphorone, is a bicyclic ketone with the molecular formula C7H10O. It is a colorless liquid with a pungent odor and is an important intermediate in the synthesis of various organic compounds, particularly in the production of pharmaceuticals, agrochemicals, and other specialty chemicals. The molecule features a seven-membered ring with a double bond and a ketone group, making it a versatile building block in organic synthesis. It is synthesized through various methods, including the Diels-Alder reaction and the Prins reaction, and is known for its chemical reactivity, particularly in cycloaddition and rearrangement reactions.

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  • 1072-77-1 Structure
  • Basic information

    1. Product Name: Bicyclo[3.2.0]hept-6-en-2-one
    2. Synonyms:
    3. CAS NO:1072-77-1
    4. Molecular Formula: C7H8O
    5. Molecular Weight: 108.14
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 1072-77-1.mol
  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: Bicyclo[3.2.0]hept-6-en-2-one(CAS DataBase Reference)
    10. NIST Chemistry Reference: Bicyclo[3.2.0]hept-6-en-2-one(1072-77-1)
    11. EPA Substance Registry System: Bicyclo[3.2.0]hept-6-en-2-one(1072-77-1)
  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 1072-77-1(Hazardous Substances Data)

1072-77-1 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 1072-77-1 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 1,0,7 and 2 respectively; the second part has 2 digits, 7 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 1072-77:
(6*1)+(5*0)+(4*7)+(3*2)+(2*7)+(1*7)=61
61 % 10 = 1
So 1072-77-1 is a valid CAS Registry Number.

1072-77-1SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 19, 2017

Revision Date: Aug 19, 2017

1.Identification

1.1 GHS Product identifier

Product name bicyclo[3.2.0]hept-6-en-4-one

1.2 Other means of identification

Product number -
Other names bicyclo<3.2.0>hept-en-2-one

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:1072-77-1 SDS

1072-77-1Upstream product

1072-77-1Relevant articles and documents

σ-bishomoaromatic heterocycles: Reactivity and synthesis of 3-oxatetracyclo[3.3.0.02,804,6]octane by photolysis at 185 nm

Klaerner, Frank-Gerrit,Dolz, Thomas,Uhlaender, Christoph,Yaslak, Salih

, p. 1385 - 1388 (2007/10/03)

The title compound 5 was produced by 185 nm photolysis of 8. The products of the 185 run photolysis can be rationalized by the assumption of the two diradical intermediates 16 and 17. At a temperature between 150 and 200°C 5 reacts with fumaronitrile 23 to give the adducts 7 and 26 in a ratio of about (5 : 1). The kinetic analysis of this reaction shows, that the adduct 7 is formed by 1,3 dipolar cycloaddition of intermediate carbonyl ylide 6.

Synthetic Photochemistry. XLVI. Cycloaddition of exo, endo-2,7-Bis(methoxycarbonyl)-11,12-dioxatetracyclo3,6.O2,7>dodeca-4,9-diene and Conjugated Enones and p-Quinones

Tian, Guan Rong,Mori, Akira,Kato, Nobuo,Takeshita, Hitoshi

, p. 506 - 513 (2007/10/02)

Photocycloaddition of exo,endo-2,7-bis(methoxycarbonyl)-11,12-dioxatetracyclo3,6.O2.7>dodeca-4,9-diene with conjugated and p-quinones occurred exclusively at the exo-addition moiety to give -cycloadducts.From cyclohexeno

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