80534-52-7Relevant academic research and scientific papers
4-ACETOXYTRICYCLO2,7>HEPT-4-EN-3-ONE; SYNTHESIS AND NOVEL BOND REORGANIZATION OF A VALENCE ISOMER OF 2-ACETOXYTROPONE
Sugihara, Yoshikazu,Yamato, Akikazu,Murata, Ichiro
, p. 3257 - 3260 (1981)
4-Acetoxytricyclo2,7>hept-4-en-3-one (3), a valence isomer of 2-acetoxytropone, was synthesized.Upon heating in pyridine at 150 deg C, 3 rearranged into 1-acetoxybicyclohepta-3,6-dien-2-one (9); the mechanism of which was examined by means of deuterium labeling experiments.
