107227-97-4Relevant academic research and scientific papers
The Structures of Bis(O-benzylxanthato)nickel(II) and the Benzene Clathrate of its 1,10-Phenanthroline Adduct
Edwards, Alison J.,Hoskins, Bernard F.,Winter, George
, p. 1983 - 1992 (2007/10/02)
The crystal and molecular structures of bis(O-benzylxanthato)nickel(II), Ni(bzxa)2, and the benzene clathrate of its 1,10-phenanthroline adduct.Ni(bzxa)2(phen).C6H6, are reported.Crystals of Ni(bzxa)2 are orthorhombic, with the space group P bca.There are four molecules per unit cell, which has dimensions a 6.961(1), b 35.008(8), c 7.277(2) Angstroem.The refinement converged with R 0.031 and Rw 0.037 after use of 1732 independent reflections for which I 2?(I).Asymmetry of the nickel-sulfur bonds is observed.The adduct crystallizes in the space group C2/c.There are four molecules each of the adduct and benzene per unit cell, which has dimensions a 7.133(3) b 18.196(5), c 24.282(5) Angstroem, β 97.01(2) deg.The refinement converged with R 0.064 and Rw 0.052 after use of 1123 independent reflections for which I 2?(I).The packing clearly indicates that this host-guest compound is of the clathrate type.
