53566-80-6

Basic information

• Product Name: {Ni(C₆H₅CH₂OCS₂)2}
• CAS NO: 53566-80-6
• Molecular Weight: 425.24
• Mol File: 53566-80-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: {Ni(C₆H₅CH₂OCS₂)2}(CAS DataBase Reference)
• NIST Chemistry Reference: {Ni(C₆H₅CH₂OCS₂)2}(53566-80-6)
• EPA Substance Registry System: {Ni(C₆H₅CH₂OCS₂)2}(53566-80-6)

Safety Data

• Hazardous Substances Data: 53566-80-6(Hazardous Substances Data)

Upstream product

• 2720-79-8 potassium benzylxanthate 
• 83864-14-6 nickel dichloride 

Downstream Products

• 107227-97-4 bis(O-benzylxanthato)(1,10-phenanthroline)nickel(II)-benzene (1/1) 

Relevant articles and documents

The Structures of Bis(O-benzylxanthato)nickel(II) and the Benzene Clathrate of its 1,10-Phenanthroline Adduct

The crystal and molecular structures of bis(O-benzylxanthato)nickel(II), Ni(bzxa)2, and the benzene clathrate of its 1,10-phenanthroline adduct.Ni(bzxa)2(phen).C6H6, are reported.Crystals of Ni(bzxa)2 are orthorhombic, with the space group P bca.There are four molecules per unit cell, which has dimensions a 6.961(1), b 35.008(8), c 7.277(2) Angstroem.The refinement converged with R 0.031 and Rw 0.037 after use of 1732 independent reflections for which I 2?(I).Asymmetry of the nickel-sulfur bonds is observed.The adduct crystallizes in the space group C2/c.There are four molecules each of the adduct and benzene per unit cell, which has dimensions a 7.133(3) b 18.196(5), c 24.282(5) Angstroem, β 97.01(2) deg.The refinement converged with R 0.064 and Rw 0.052 after use of 1123 independent reflections for which I 2?(I).The packing clearly indicates that this host-guest compound is of the clathrate type.